A siloxane is a functional group in organosilicon chemistry with the Si−O−Si linkage. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H(OSiH2)nOH and (OSiH2)n. Siloxanes also include branched compounds, the defining feature of which is that each pair of silicon … Meer weergeven Siloxanes generally adopt structures expected for linked tetrahedral ("sp -like") centers. The Si−O bond length is 1.64 Å (vs Si–C distance of 1.92 Å) and the Si-O-Si angle is rather open at 142.5°. By contrast, the C−O … Meer weergeven Oxidation of organosilicon compounds, including siloxanes, gives silicon dioxide. This conversion is illustrated by the combustion of hexamethylcyclotrisiloxane: ((CH3)2SiO)3 + 12 O2 → 3 SiO2 + 6 CO2 + 9 H2O Strong base … Meer weergeven Cyclomethicones are a group of methyl siloxanes, a class of liquid silicones (cyclic polydimethylsiloxane polymers) that possess the … Meer weergeven • Christoph Rücker, Klaus Kümmerer: Environmental Chemistry of Organosiloxanes. In: Chemical Reviews. 115(1), 2015, p. 466–524, doi: Meer weergeven The main route to siloxane functional group is by hydrolysis of silicon chlorides: 2 R3Si−Cl + H2O → R3Si−O−SiR3 + 2 HCl The reaction … Meer weergeven Polysiloxanes (silicones), upon combustion in an inert atmosphere, generally undergo pyrolysis to form silicon oxycarbide or silicon carbide (SiC). By exploiting … Meer weergeven Because silicones are heavily used in biomedical and cosmetic applications, their toxicology has been intensively examined. "The inertness of silicones toward warmblooded animals has been demonstrated in a number of tests." With an LD50 in … Meer weergeven

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